四川盆地广安地区中二叠统栖霞组岩石特征与沉积环境     

易海永  崔宝琛  王瑶琳  邱玉超  徐胜林  李乾 《吉林大学学报(地球科学版)》2020,50(2):454-464

四川盆地中二叠统栖霞组勘探发现系列油气，资源潜力巨大。但广安地区中二叠统栖霞组的岩石学特征及沉积环境研究薄弱。在野外地质调查的基础上，结合室内岩石学、岩相学等综合分析，对广安地区栖霞组碳酸盐岩岩石特征、沉积相类型及其古地理展布特征进行了系统研究。结果表明：广安地区栖霞组主要发育亮晶颗粒灰岩、亮晶生物碎屑灰岩、微晶生物碎屑灰岩、微晶颗粒灰岩、生物碎屑微晶灰岩、含生物碎屑微晶灰岩和泥晶灰岩7种岩石类型；碳酸盐岩颗粒主要以生物碎屑为主，部分层位发育球粒；古生物化石以三叶虫、腕足和有孔虫为主，同时可见棘皮类和藻类；栖霞组沉积期主要为碳酸盐岩台地沉积环境，其中栖霞组晚期（栖二段）台缘滩和台内滩较为发育，为该区油气成藏提供了有利条件。  相似文献   

勉略构造带新元古代洋盆俯冲作用：来自略阳地区纸房沟岩片火山岩锆石U- Pb年龄和Lu- Hf同位素的证据     

徐通  张晓团  焦建刚  张红强  贾力 《地质学报》2020,94(12):3607-3624

纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究，将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾，富Na贫P，整体具有N- MORB特点，形成于洋脊构造环境。相比Ⅰ类火山岩，Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量，相对亏损Nb、Ta、P和Ti，形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示，εHf(t)值主体为负值，介于-8.01~+0.77，表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15)，表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为，纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物，俯冲作用一直持续到800Ma左右，该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。  相似文献   

帕米尔高原Rushan-Pshart古特提斯洋或中特提斯洋争论的岩石地球化学证据     

徐天德  王世锋  汤文坤  姚鑫 《地质科学》2020,(1):218-233

帕米尔高原上广泛分布的加里东期火山岩,印支期火山岩与燕山期火山岩被认为是块体依次向北俯冲拼贴到欧亚板块上的产物。特别是燕山期火山岩被认为是Rushan-Pshart中特提斯洋闭合的产物。但近年来地层古生物、火山岩证据不断表明Rushan-Pshart洋闭合时间在晚三叠一早侏罗世,由此限定Rushan-Pshart古特提斯洋性质,而帕米尔高原上广泛分布的燕山期火山岩是更南部的Shyok中特提斯洋闭合的产物。目前,中国境内Rushan-Pshart缝合带属性的研究工作展开较晚,研究程度较低。我们对塔什库尔干明铁盖沟一线燕山期火山岩带展开的工作发现零星分布的印支期花岗岩。印支期花岗岩错石U・Pb年龄显示岩体侵位时间在201 Ma左右。全岩主量元素特征表明岩石为I型高钾钙碱性闪长花岗岩;稀土元素在球粒陨石标准化图解中呈轻稀土元素相对富集,重稀土元素相对亏损的右倾海鸥型。明铁盖岩体的微量元素显示大离子亲石元素明显富集,而高场强元素明显亏损。稀土微量元素特征倾向花岗岩属性为岛弧型花岗岩,Sr-Nd-Hf同位素比值特征显示岩体形成于下地壳部分熔融环境。岩体的地化特征表明岩体形成的构造环境为板块汇聚的洋壳俯冲阶段,结合区域地质特征,我们将花岗岩体归为Rushan-Pshart古特提斯洋壳俯冲消减的产物。Rushan-Pshart缝合带传统上认为是中特提斯带,近年的研究进展认为其为古特提斯缝合带,本文的工作支持这种观点。Rushan-Pshart古特提斯缝合带的确立对帕米尔高原与青藏高原主体的块体对比提供了可信的对比方案,并对青藏高原新生代陆内变形方式的争论提供了可靠的证据。  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

Transcriptomic analysis reveals the effect of the exopolysaccharide of Psychrobacter sp. B-3 on gene expression in RAW264.7 macrophage cells     

ZHANG Pingping  LI Jiang  YU Leiye  WEI Jingfang  XU Tong  SUN Guojie 《海洋学报(英文版)》2018,(8)

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Petrogenesis of Early Cretaceous hornblende gabbro in Khanka Massif: evidence from geochronology and geochemistry     

WEI Chunxia  WEI Xu  ZHU Weigang  XU Wenliang 《世界地质(英文版)》2018,(3)

The authors report zircon U-Pb geochronological,whole-rock geochemical and zircon Lu-Hf isotope data for the hornblende gabbro within the Khanka Massif,with the aim of constraining its formation time and petrogenesis. The zircon U-Pb dating shows that ~(206)Pb/~(238)Pb ages of zircons from the hornblende gabbro range from 120 to 129 Ma,yielding a weighted mean age of 123 ± 2 Ma,i. e.,the Early Cretaceous. The hornblende gabbro has SiO_2 of 44. 77%--46. 58% and belongs to the tholeiitic series on FeO~t/MgO-SiO_2 diagram. It displays a right-inclined REE pattern with( La/Yb)_N ratios of 3. 44 to 4. 42. The trace element spidergram shows that they are enriched in large ion lithophile elements( LILE) such as Rb,Th,U,K and Pb,and depleted in high field strength elements( HFSE) such as Nb,Ta,Ti and P,indicating an affinity to arc igneous rocks.The ε_(Hf)( t) values of zircons vary from -2. 6 to + 3. 9 and Hf model ages( T_(DM1)) range from 622 to 883 Ma.These geochemical characteristics indicate that primary magma of the hornblende gabbro could be derived from partial melting of young mantle material accreted during the Neoproterozoic. Combined with the Early Cretaceous igneous rock assemblages in NE Asia. It is concluded that the hornblende gabbro formed in an active continental margin related to the westward subduction of the Paleo-Pacific Plate beneath the Khanka Massif.  相似文献   

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Regional Characteristics and Causes of Haze Events in Northeast China     

Weiwei Chen  Shichun Zhang  Quansong Tong  Xuelei Zhang  Hongmei Zhao  Siqi Ma  Aijun Xiu  Yuexin He 《中国地理科学(英文版)》2018,28(5):836-850

Northeast China experiences severe atmospheric pollution, with an increasing occurrence of heavy haze episodes. However, the underlying forces driving haze formation during different seasons are poorly understood. In this study, we explored the spatio-temporal characteristics and causes of haze events in Northeast China by combining a range of data sources(i.e., ground monitoring, satellite-based products, and meteorological products). It was found that the ‘Shenyang-Changchun-Harbin(SCH)'city belt was the most polluted area in the region on an annual scale. The spatial distribution of air quality index(AQI) values had a clear seasonality, with the worst pollution occurring in winter, an approximately oval-shaped polluted area around western Jilin Province in spring, and the best air quality occurring in summer and most of the autumn. The three periods that typically experienced intense haze events were Period I from mid-October to mid-November(i.e., late autumn and early winter), Period II from late-December to February(i.e., the coldest time in winter), and Period III from April to mid-May(i.e., spring). During Period I, strong PM_(2.5) emissions from seasonal crop residue burning and coal burning for winter heating were the dominant reasons for the occurrence of extreme haze events(AQI 300). Period II had frequent heavy haze events(200 AQI 300) in the coldest months of January and February, which were due to high PM_(2.5) emissions from coal burning and vehicle fuel consumption, a lower atmospheric boundary layer, and stagnant atmospheric conditions. Haze events in Period III, with high PM_(10) concentrations, were primarily caused by the regional transportation of windblown dust from degraded grassland in central Inner Mongolia and bare soil in western Jilin Province. Local agricultural tilling could also release PM_(10) and enhance the levels of windblown dust from tilled soil. Better control of coal burning, fuel consumption, and crop residue burning in winter and autumn is urgently needed to address the haze problem in Northeast China.  相似文献   

Explicit stress–strain equations for modeling frictional materials     

Kenneth J. Xu  Martin D. Liu  Buddhima Indraratna 《Marine Georesources & Geotechnology》2018,36(6):722-734

In this paper, a comprehensive study on simulating the shearing behavior of frictional materials is performed. A set of two explicit equations, describing the relationship among the shear stress ratio and the distortional strain and the volumetric strain, are formulated independently. The equations contain three stress parameters and three strain parameters and another parameter representing the nonuniformity of stress and strain during softening. All the parameters have clear physical significance and can be determined experimentally. It is demonstrated that the proposed equations have the capacity of simulating the complicated shearing behavior of many types of frictional materials including geomaterials. The proposed equations are used to simulate the stress–strain behavior for 27 frictional materials with 98 tests. These materials include soft and stiff clays in both reconstituted and structured states, silicon sands and calcareous sands, silts, compacted fill materials, volcanic soils, decomposed granite soils, cemented soils (both artificially and naturally cemented), partially saturated soils, ballast, rocks, reinforced soils, tire chips, sugar, wheat, and rapeseed. It has been demonstrated that the proposed explicit constitutive equations have the capacity to capture accurately the shearing behavior of frictional materials both qualitatively and quantitatively. A study on model parameters has been performed.  相似文献   

泉水流量、电导率、pH值动态变化研究     

余保汶  肖敏杰  王旭  费璇 《地质与资源》2020,29(4):380-387

岩溶水是指赋存于岩溶孔隙中的地下水，是我国南方生产生活主要用水来源.随着社会对水资源需求的逐步扩大，岩溶水资源的开发利用越发重要.通过定期监测岳麓山泉水流量、电导率、pH值，结合岳麓山岩土层性质和长沙市降雨量，采用统计分析和Spearman秩相关系数法对泉水流量变化和泉水水质定性评价进行研究.研究结果表明，大气降雨对岩溶水进行补给从而使泉水流量增大，泉水流量的改变除与降雨量有关外，还受土壤入渗率和降雨时长的影响.采用Spearman秩相关系数法可定量计算电导率与时间的相关性，间接判断周围环境对泉水水质影响的难易程度，有利于识别电导率代表性位置泉眼，更好地监测和评价岩溶水.土壤酸沉降污染严重或酸雨频繁地区易导致岩溶水pH值呈酸性.对泉水流量和水质的研究有利于科学开发利用岩溶水资源.  相似文献